A process to increase the detonation resistance of motor gasoline using a component obtained during needle coke production
R.R. Gabdulkhakov, K.Yu. Govkelevich, V.A. Rudko, I.N. Pyagay
Empress Catherine II Saint Petersburg Mining University, Saint Petersburg, Russian Federation
Russian Mining Industry №1S / 2025 p. 21-27
Abstract: The paper discusses the effect of polymer addition, which improves needle coke morphology, on the composition and properties of fuel distillate fractions of the delayed coking process. A significant change was found in the hydrocarbon composition and physicochemical properties of the cracked gasoline fraction along with preserved composition of the light and heavy gasoil fractions, as well as a significant change in the material balance of the process. When mixing 35 wt% of the gasoline fraction of the coking distillates made using the modified feedstock with gasoline which octane number is 80.0, we observe an increase in the detonation resistance of the fuel by 9.7 points, while addition of the gasoline fraction from the standard coking gasoline leads to a decrease in this indicator by 10.2 points. The obtained results indicate a significant contribution of the 10 wt% polymer additive to the quality characteristics not only of the carbon material, but also of the coking gasoline fraction. The change in the composition and qualitative characteristics of the gasoline fraction has a significant impact on the marketing chain of this fraction as a component of motor fuel. Due to predominance of the high-octane monoaromatic compounds, this fraction has a higher detonation resistance than the same fraction obtained by coking the non-modified feedstock.
Keywords: coking, needle coke, polymer modification, fuels, gasoline fraction, detonation resistance
For citation: Gabdulkhakov R.R., Govkelevich K.Yu., Rudko V.A., Pyagay I.N. A process to increase the detonation resistance of motor gasoline using a component obtained during needle coke production. Russian Mining Industry. 2025;(1S):21–27. https://doi.org/10.30686/1609-9192-2025-1S-21-27
Article info
Received: 09.01.2025
Revised: 11.02.2025
Accepted: 11.02.2025
Information about the authors
Renat R. Gabdulkhakov – Cand. Sci. (Eng.), Senior Research Associate, Research Center for Problems of Mineral and Anthropogenic Resources Processing, Empress Catherine II Saint Petersburg Mining University, Saint Petersburg, Russian Federation; https://orcid.org/0000-0001-7243-2468; e-mail: Gabdulkhakov_RR@pers.spmi.ru
Kseniya Yu. Govkelevich – Student, Department of Chemical Technology and Energy Processing, Empress Catherine II Saint Petersburg Mining University, Saint Petersburg, Russian Federation
Viacheslav A. Rudko – Cand. Sci. (Eng.), Executive Director, Research Center for Problems of Mineral and Anthropogenic Resources Processing, Empress Catherine II Saint Petersburg Mining University, Saint Petersburg, Russian Federation; https://orcid.org/0000-0002-8527-6705; e-mail: Rudko_VA@pers.spmi.ru
Igor N. Pyagay – Dr. Sci. (Eng.), Academic Advisor, Research Center for Problems of Mineral and Anthropogenic Resources Processing, Empress Catherine II Saint Petersburg Mining University, Saint Petersburg, Russian Federation; e-mail: Pyagay_IN@pers.spmi.ru
Authors’ contribution
Renat R. Gabdulkhakov – preparation of the main text of the article, carrying out the experimental studies; processing of the test data.
Kseniya Yu. Govkelevich – carrying out experimental studies of the fractional and hydrocarbon composition of fractions.
Viacheslav A. Rudko – methodology, studies of the octane number, reviewing of the article.
Igor N. Pyagay – scientific supervision, reviewing of the article.
References
1. Sharikov Yu.V., Sharikov F.Yu., Krylov K.A. Mathematical model of optimum control for petroleum coke production in a rotary tube kiln. Theoretical Foundations of Chemical Engineering. 2021;55(4):711–719. https://doi.org/10.1134/S0040579521030192
2. Литвиненко В.С., Петров Е.И., Василевская Д.В., Яковенко А.В., Наумов И.А., Ратников М.А. Оценка роли государства в управлении минеральными ресурсами. Записки Горного института. 2023;259:95–111. https://doi.org/10.31897/PMI.2022.100 Litvinenko V.S., Petrov E.I., Vasilevskaya D.V., Yakovenko A.V., Naumov I.A., Ratnikov M.A. Assessment of the role of the state in the management of mineral resources. Journal of Mining Institute. 2023;259:95–111. https://doi.org/10.31897/PMI.2022.100
3. Guan Z., Sun G., Feng C., Li J., Wang M., Guo M. et al. Ni/ZSM-5@Ni/ZnO catalysts for fluid catalytic cracking gasoline desulfurization-aromatization tandem reactions. Fuel. 2025;381(C):133613. https://doi.org/10.1016/j.fuel.2024.133613
4. Abdellatief T.M.M., Ershov M.A., Abdelkareem M.A., Mustafa A., Jamil F., Kapustin V.M. et al. A unifying methodology for gasoline-grade biofuel from several renewable and sustainable gasoline additives. Process Safety and Environmental Protection. 2024;190:1386–1402. https://doi.org/10.1016/j.psep.2024.07.112
5. Savelenko V.D., Ershov M.A., Kapustin V.M., Klimov N.A., Burov N.O., Aleksanyan D.R. et al. A research-inducing environment to technology using friction modifier for motor gasoline fuel. Process Safety and Environmental Protection. 2024;190:792–803. https://doi.org/10.1016/j.psep.2024.07.056
6. Kakani R., Ahmad Z.N., Willoughby A., Adekanbi M., Holloway E., Shaver G.M. et al. Impact of cylinder deactivation on fuel efficiency in off-road heavy-duty diesel engines during high engine speed operation. Applied Thermal Engineering. 202;257(B):124333. https://doi.org/10.1016/j.applthermaleng.2024.124333
7. Safiullin R., Efremova V., Ivanov B. The method of multi-criteria evaluation of the effectiveness of the integrated control system of a highly automated vehicle. The Open Transportation Journal. 2024;18:e18744478309909. https://doi.org/10.2174/0118744478309909240807051315
8. Safiullin R.N., Safiullin R.R., Sorokin K.V., Kuzmin K.A., Rudko V.A. Integral assessment of influence mechanism of heavy particle generator on hydrocarbon composition of vehicles motor fuel. International Journal of Engineering. 2024;37(8):1700– 1706. https://doi.org/10.5829/ije.2024.37.08b.20
9. Mohamed S., Hassan M. Optimization of delayed coker unit process variables for enhancement of product yields. Journal of Petroleum and Mining Engineering. 2024;25(2):45–62. https://doi.org/10.21608/jpme.2024.217836.1168
10. Safiullin R.N., Reznichenko V.V., Safiullin R.R. The software adaptive system for managing the heavy cargo transportation process based on the automated vehicle weight and size control system. Journal of Physics: Conference Series. 2021;1753:012063. https://doi.org/10.1088/1742-6596/1753/1/012063
11. Safiullin R., Arias Z.P. Comprehensive assessment of the effectiveness of passenger transportation processes using intelligent technologies. The Open Transportation Journal. 2024;18:e26671212320514. https://doi.org/10.2174/0126671212320514240611100437
12. Гендлер С.Г., Братских А.С. Актуальные проблемы возгорания угольных скоплений в породных отвалах. Горная промышленность. 2024;(5S):71–77. https://doi.org/10.30686/1609-9192-2024-5S-71-77 Gendler S.G., Bratskih A.S. Actual problems of coal accumulations ignition in rock dumps. Russian Mining Industry. 2024;(5S):71–77. (In Russ.) https://doi.org/10.30686/1609-9192-2024-5S-71-77
13. Мустафаев А.С., Сухомлинов В.С., Бажин В.Ю., Буковецкий Н.А., Суров А.В. Плазменная технология получения сверхчистого корунда. Цветные металлы. 2024;(4):21–29. https://doi.org/10.17580/tsm.2024.04.03 Mustafaev А.S., Sukhomlinov V.S., Bazhin V.Yu., Bukovetskiy N.A., Surov А.V. Plasma technology for producing ultrapure corundum. Tsvetnye Metally. 2024;(4):21–29. (In Russ.) https://doi.org/10.17580/tsm.2024.04.03
14. Свергузова С.В., Сапронова Ж.А., Зубкова О.С., Святченко А.В., Шайхиева К.И., Воронина Ю.С. Пыль электросталеплавильного производства как сырье для получения коагулянта. Записки Горного института. 2023;260:279–288. https://doi.org/10.31897/PMI.2023.23 Sverguzova S.V., Sapronova Z.A., Zubkova O.S., Svyatchenko A.V., Shaikhieva K.I., Voronina Y.S. Electric steelmaking dust as a raw material for coagulant production. Journal of Mining Institute. 2023;260:279–288. https://doi.org/10.31897/PMI.2023.23
15. Горланов Е.С., Леонтьев Л.И. Направления технологического развития алюминиевых электролизеров. Записки Горного института. 2024;266:246–259. Режим доступа: https://pmi.spmi.ru/pmi/article/view/16291 (дата обращения: 11.12.2024). Gorlanov Е.S., Leontev L.I. Directions in the technological development of aluminium pots. Journal of Mining Institute. 2024;266:246–259. Available at: https://pmi.spmi.ru/pmi/article/view/16291 (accessed: 11.12.2024).
16. Литвинова Т.Е., Герасёв С.А. Поведение фосфата церия (III) в карбонатно-щелочной среде. Записки Горного института. 2024:1–8. Режим доступа: https://pmi.spmi.ru/pmi/article/view/16416 (дата обращения: 18.11.2024). Litvinova T.E., Gerasev S.A. Behaviour of cerium (III) phosphate in a carbonate-alkaline medium. Journal of Mining Institute. 2024:1–8. Available at: https://pmi.spmi.ru/pmi/article/view/16416 (accessed: 18.11.2024).
17. Safiullin R., Epishkin A., Safiullin R., Haotian T. Method of forming an integrated automated control system for intelligent objects. In: Ceur workshop proceedings: Proceedings of the 2nd International Scientific and Practical Conference “Information Technologies and Intelligent Decision Making Systems” (ITIDMS-II-2021). Aachen, Germany; 2021, pp. 17–26.
18. Фещенко Р.Ю., Ерохина О.О., Литаврин И.О., Рябошук С.В. Повышение окислительной стойкости графитированных электродов дуговых печей. Черные металлы. 2023;(7):31–36. https://doi.org/10.17580/chm.2023.07.03 Feshchenko R.Yu., Erokhina O.O., Litavrin I.O., Ryaboshuk S.V. Improvement of oxidation resistance of arc furnace graphite electrodes. Chernye Metally. 2023;(7):31–36. (In Russ.) https://doi.org/10.17580/chm.2023.07.03
19. Поваров В.Г., Ефимов И.И. Применение модели UNIFAC в расчете физико-химических свойств экотоксикантов для технологических и экоаналитических целей. Записки Горного института. 2023;260:238–247. https://doi.org/10.31897/PMI.2023.41 Povarov V.G., Efimov I.I. Use of the UNIFAC model in the calculation of physicochemical properties of ecotoxicants for technological and ecoanalytical purposes. Journal of Mining Institute. 2023;260:238–247. https://doi.org/10.31897/PMI.2023.41
20. Гоголинский К.В., Ивкин А.Е., Алехнович В.В., Васильев А.Ю., Тюрнина А.Е., Васильев А.С. Оценка показателей точности определения толщины покрытий методом шарового истирания. Заводская лаборатория. Диагностика материалов. 2020;86(7):39–44. https://doi.org/10.26896/1028-6861-2020-86-7-39-44 Gogolinsky K.V., Ivkin A.E., Alekhnovich V.V., Vasiliev A.Yu., Tyurnina A.E., Vasiliev A.S. Evaluation of the accuracy indicators in determination of the coating thickness by crater grinding method. Industrial Laboratory. Diagnostics of Materials. 2020;86(7):39–44. (In Russ.) https://doi.org/10.26896/1028-6861-2020-86-7-39-44